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<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:dc="http://purl.org/dc/elements/1.1/"><rdf:Description rdf:about="https://dk.um.si/IzpisGradiva.php?id=66357"><dc:title>Synthesis and structure of transition metal bisalkinylselenolato complexes</dc:title><dc:creator>Pietschnig,	Rudolf	(Avtor)
	</dc:creator><dc:creator>Moser,	Carmen	(Avtor)
	</dc:creator><dc:creator>Spirk,	Stefan	(Avtor)
	</dc:creator><dc:creator>Schäfer,	Sven	(Avtor)
	</dc:creator><dc:subject>analytical chemistry</dc:subject><dc:subject>isomers</dc:subject><dc:subject>stability</dc:subject><dc:subject>metals</dc:subject><dc:description>We synthesized closely related cis and trans platinum complexes of SeCC-n-C5H11 and elucidated their structures in solution and the crystalline state. In line with previous work we find exclusive coordination of the selenium atom of the ambident alkynylselenolate ligand and a preference for the obviously more stable trans isomer. In contrast to previous work we find auniform increase of all metal ligand bond lengths in the cis vs. the trans isomers. Moreover we studied the coordination of alkynykselenolate ligands to group 4 metals.</dc:description><dc:date>2005</dc:date><dc:date>2017-06-22 09:04:39</dc:date><dc:type>Znanstveno delo</dc:type><dc:identifier>66357</dc:identifier><dc:language>sl</dc:language></rdf:Description></rdf:RDF>