20.500.12556/DKUM-14360 Sinteza in karakterizacija nikljevih(II) acetatov z aminopiridini Synthesis and characterisation of nickel(II) acetate with aminopyridines Namen diplomske naloge je bila sinteza novih nikljevih koordinacijskih spojin iz nikljevega(II) acetata tetrahidrata in aminopiridinov. Najprej smo sintetizirali nikljev(II) hidroksid, ki smo ga potem uporabili za sintezo nikljevega(II) acetata tetrahidrata. Sintetizirane kristale smo karakterizirali z rentgensko praškovno difrakcijo, termogravimetrično analizo, diferenčno dinamično kalorimetrijo, Fourierjevo transformacijsko infrardečo spektroskopijo, izmerili susceptibilnost in magnetizacijo ter izvedli monokristalno analizo. Delo je bilo namenjeno predvsem odkrivanju še nesintetiziranih nikljevih koordinacijskih spojin, določanju njihove kemijske formule ter spoznavanju različnosti in podobnosti sintetiziranih nikljevih koordinacijskih spojin ob uporabi različnih množinskih razmerij kemikalij, potrebnih za sintezo. The purpose of this diploma work was to synthesize new nickel coordination compounds out of nickel(II) acetate tetrahydrate and aminopyridines. First we synthesized nickel(II) hydroxide, which was further on used to synthesize nickel(II) acetate tetrahydrate. Using the X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), magnetic measurements (susceptibility and magnetization of the samples) and single crystal X-ray structure analysis I characterised the synthesized crystals. The work is concentrated on the discovery of unsynthesized nickel coordination compounds, determining their chemical formula and acknowledging the diversity and likeness of synthesized nickel coordination compounds while having in mind different molar concentration of chemicals needed for synthesis. nikljev acetat tetrahidrat aminopiridin koordinacijske spojine termogravimetrična analiza (TGA) diferenčna dinamična kalorimetrija (DSC) rentgenska praškovna difrakcija (RPD) monokristalna analiza Fourierjeva transformacijska infrardeča spektroskopija (FTIR) magnetne meritve (merjenje susceptibilnosti in magnetizacije vzorcev) nickel acetate tetrahydrate aminopyridine nickel coordination compunds X-ray powder diffraction (XRD) thermogravimetric analysis (TGA) differential scanning calorimetry (DSC) single crystal X-ray structure analysis Fourier transform infrared spectroscopy (FTIR) magnetic measurements (susceptibility and magnetization of the samples) true true false [D. Korpar] Slovenski jezik Angleški jezik Diplomsko delo 2010-06-09 14:08:59 2010-07-08 15:41:01 2022-04-12 21:57:59 2023-12-17 03:33:08 2010 0 Maribor 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 54(043.2) 17748232 URN:SI:UM:DK:4YQGFMVW UNI_Korpar_Danijel_2010.pdf UNI_Korpar_Danijel_2010.pdf 1 EBC7760F22B4191CDF856CE2070AFDAA fa9ef652cfa700dfc05713ada073c48bbab21f85de4e9feeb850b0937eff1906 22c4c3bc-7c04-11eb-bb7a-00155d0001ca 20.500.12556/dkum/d5d514f6-724e-466f-9de7-6d15b42b001b https://dk.um.si/Dokument.php?lang=slv&id=15250 Fakulteta za naravoslovje in matematiko 0 0 0