20.500.12556/DKUM-19357 ŠTUDIJ POVRŠINSKE OBDELAVE PIGMENTNIH DELCEV TiO 2 Z ANORGANSKIMI MATERIALI STUDY OF PIGMENTARY TiO 2 SURFACE TREATMENT WITH INORGANIC MATERIALS V diplomskem delu smo s sistematičnim pristopom izvedli postopek površinske obdelave pigmentnega titanovega dioksida (TiO2), saj le-ta igra pomembno vlogo pri izboljšanju lastnosti TiO2 (optične lastnosti, vremenska obstojnost in fotostabilnost). S homogenimi, transparentnimi plastmi anorganskih hidratiziranih oksidov (SiO2 in/ali Al2O3) na površini TiO2 želimo omejiti vpliv negativnega delovanja zunanjih dejavnikov na lastnosti premazov za zunanje aplikacije. Površinska obdelava zahteva poglobljeno poznavanje in razumevanje osnov koloidne kemije. Postopek je zelo kompleksen in dinamičen ter ga lahko z uravnavanjem ustreznih parametrov vodimo v želeno smer. Na morfologijo nanosa in posledično na končne lastnosti pigmenta vplivajo procesni pogoji (temperatura, vrednost pH, hitrost postopka, izbira prekurzorja, zaporedje korakov). Zato je raziskava obsegala analizo vseh vhodnih surovin in preučitev številnih procesnih parametrov. Pri površinski obdelavi smo uporabili natrijev silikat (Na2SiO3) kot vir SiO2 in natrijev aluminat (NaAlO2) kot vir Al2O3. Uspešnost površinske obdelave TiO2 delcev smo določili z uporabo vrstične in presevne elektronske mikroskopije (SEM in TEM), medtem ko smo spremembo elektrokinetičnih lastnosti delcev pred in po površinski obdelavi določili s pomočjo aparata za določanje površinskega naboja delcev (PCD). Z BET analizatorjem smo izmerili specifično površino delcev, funkcionalne skupine na površini pigmenta pa smo določili z FTIR aparaturo. Within this work a systematic approach of TiO2 pigment surface treatment was carried out. Surface treatment plays a significant role in the sense of TiO2 properties improvement (optical properties, weather resistance, and photo stability). With the intention of improvement of pigmentary properties, homogeneous, transparent layers of inorganic hydrated oxides (SiO2 and/or Al2O3) on the surface of pigmentary TiO2 were formed to suppress the influence of external weather conditions. Surface treatment requests a deeper understanding of colloidal chemistry principles. The process is complex and dynamic and could be governed into the desired direction, when controlling the adequate conditions. Layer morphology and final properties of surface treated pigment are affected by process conditions (temperature, pH, process speed, precursor, the sequence of process steps). For that reason, the research comprehends the raw materials analysis and process conditions examination. Sodium silicate (Na2SiO3) was used as a source of SiO2 and sodium aluminate (NaAlO2) was used as a source of Al2O3. The effectiveness of surface treatment was determined using scanning (SEM) and transmission (TEM) electron microscopy, while the changes in TiO2 electrochemical properties before and after surface treatment were determined using particle charge detector (PCD). The BET analyzer was measured BET specific surface area of particles. The functional groups on the surface of the pigments were determined by FTIR device. Pigmentni TiO2 površinska obdelava izobarjanje anorganski hidratizirani oksidi SiO2 in Al2O3. Pigmentary TiO2 surface treatment precipitation inorganic hydrated oxides SiO2 and Al2O3. true true false [M. Lešnik] Slovenski jezik Angleški jezik Diplomsko delo 2011-07-07 10:15:32 2011-07-14 08:16:46 2022-04-13 15:18:51 2023-12-25 03:19:21 2011 0 Maribor 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 549.514:[667.622.2:661.882](043.2) 15225110 URN:SI:UM:DK:9F8SWWMY UNI_Lesnik_Maja_2011.pdf UNI_Lesnik_Maja_2011.pdf 1 6025AC7584949BFA72801CB2E645320E 76050a387f2ff0e49eebc7f9029a2ee32884d790f1fa2d8568ca87f60cf7b5ef 5b48481b-7c05-11eb-bb7a-00155d0001ca 20.500.12556/dkum/78221c84-8586-406c-8f27-8061f155c5f7 https://dk.um.si/Dokument.php?lang=slv&id=23374 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0