20.500.12556/DKUM-27105 Oil-in-water high internal phase emulsions for porous monolithic polymers Porous monolithic polymers are objects of many studies recently due to their wide applicability. Especially in separation methods use of monoliths is growing. Usually, porous monoliths are prepared by bulk polymerisation with the use of porogenic solvents. An alternative way of preparation is to polymerise the continuous phase of an emulsion. When the volume fraction of the internal phase exceeds 74%, the emulsion is called a HIPE (high internal phase emulsion), and a polymer derived from it, a PolyHIPE. PolyHIPEs of styrene, vinylbenzyl chloride and acrylate chemistry have been prepared from awater in oil emulsion system, where monomers are dissolved in the organic phase. We describe the reversed procedure, an oil in water high internal phaseemulsion, where monomers are water soluble. Porous polymers based on acrylic acid and crosslinked with methylenebisacrylamide were prepared by using a high internal phase emulsion with toluene as the oil phase. The influence of initiator and surfactant on the morphology was studied. organic chemistry porous monolith polymers polymer supports preparation emulsion polymerization HIPE organska kemija porozni monolitni polimeri polimerni nosilci priprava emulzijska polimerizacija HIPE true false false Angleški jezik Angleški jezik Neznano 2012-06-01 09:48:46 2012-06-01 09:48:46 2022-04-15 03:43:29 2019-07-10 12:12:00 2005 0 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 547:678 10170646 1618-7229 URN:SI:UM:DK:LV4PT62G http://www.e-polymers.org/papers/KrajncPeter_161205.pdf 1 https://dk.um.si/Dokument.php?lang=slv&id=36342 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0