20.500.12556/DKUM-63008 UPORABA TERMOGRAVIMETRIČNE METODE PRI KARAKTERIZACIJI KOORDINACIJSKIH SPOJIN APPLICATION OF THERMOGRAVIMETRIC METHOD IN THE CHARACTERIZATION OF COORDINATION COMPOUNDS Namen diplomskega dela je ugotavljanje primernosti termogravimetrične analize pri karakterizaciji različnih koordinacijskih spojin. Karakterizirala sem že pripravljene koordinacijske spojine, dobro raziskano modro galico in manj znane hidroksilamonijeve fluoromanganate. Karakterizirala sem tudi cinkove koordinacijske spojine, ki sem jih sintetizirala iz cinkovega(II) acetata dihidrata in piridinkarboksamida (nikotinamid, izonikotinamid) v etanolu oziroma metanolu. Sintezne reakcije so potekale pri sobni temperaturi pri mešanju in refluksu. Preverjala sem tudi obstojnost pri hranjenju vzorcev, primerjala metodi mešanja in refluksa ter ugotavljala, če ima izbira topila vpliv na nastal produkt. The purpose of my diploma thesis is to assess the adequacy of thermogravimetric analysis in characterization of different coordination compounds. I have characterized pre-prepared coordination compounds, e.g. well researched copper sulphate and less known hydroxylammonium fluoromanganate. I have also characterized zinc coordination compounds, which I have synthesized from zinc(II) acetate dihydrate and pyridinecarboxamide (nicotinamide, isonicotineamide) in ethanol or methanol. Synthesis reactions have been carried out at room temperature while mixing and reflux. I have also been testing the stability of stored samples, I have compared the methods of mixing and reflux, and been researching whether the choice of a solvent influences the outcome product. koordinacijske spojine termogravimetrična analiza (TGA) rentgenska praškovna difrakcija (RPD) cinkov(II) acetat hidrat nikotinamid izonikotinamid hidroksilamonijevi fluoromanganat coordination compounds thermogravimetric analysis (TGA) X-ray diffraction (XRD) zinc(II) acetate hydrate nicotinamide isonicotinamide hydroxylammonium fluoromanganates true true false [T. Ahej] Slovenski jezik Angleški jezik Diplomsko delo 2016-09-05 10:49:40 2016-10-04 14:33:22 2022-07-01 03:08:05 2019-07-11 13:13:44 2016 0 Maribor 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 544.016.2:543.573(043.2) 20313878 URN:SI:UM:DK:JDIHA8UA UN_Ahej_Tjasa_2016.pdf UN_Ahej_Tjasa_2016.pdf 1 1ECCBE63C212488672C13E565002D5CF e53379d2c1e8ab292a5fd82c5de2baae1b6782b3c9ff50e43d0e2b7159fd18df 850f569f-7c0d-11eb-bb7a-00155d0001ca https://dk.um.si/Dokument.php?lang=slv&id=105050 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0