20.500.12556/DKUM-72797 Sinteza koordinacijskih spojin železa s piridinkarboksamidi (pikolinamid, nikotinamid, izonikotinamid) Synthesis of iron coordination compounds with pyridine carboxamides Namen magistrskega dela je bila sinteza in karakterizacija novih koordinacijskih spojin železa z izbranimi piridinkarboksamidi (pikolinamid, nikotinamid in izonikotinamid). Opravljenih je bilo 20 sintez, pri katerih smo spreminjali sintezne pogoje in izbrane reagente. Najpogosteje uporabljeno topilo je bilo metanol. Sintezne produkte smo karakterizirali z rentgensko praškovno difrakcijo, infrardečo spektroskopijo in strukturno analizo na monokristalu. Uspelo nam je sintetizirati novo koordinacijsko spojino s kemijsko formulo (isnH)2[Fe(isn)2(SO4)2(H2O)2]·H2O, katere struktura do sedaj še ni bila opisana. Spojina je bila produkt dveh sintez (NB19 in NB20), pri katerih smo kot reagenta uporabili izonikotinamid in železov(II) sulfat heptahidrat. Sintezi smo izvedli z mešanjem pod refluksom. The purpose of this Master thesis was the synthesis and characterization of the new iron coordination compounds with pyridinecarboxamides (picolineamide, nicotinamide and isonicotinamide). We performed 20 synthesis, in which we changed conditions and the selected reagents. The most commonly used solvent was methanol. The synthesis products were characterized by X-ray powder diffraction, infrared spectroscopy and single-crystal X-ray diffraction. We succeeded to synthesize new coordination compound with chemical formula (isnH)2[Fe(isn)2(SO4)2(H2O)2]·H2O. The compound´s structure has not yet been known. It was the synthesis product of two syntheses (NB19 in NB20), where the isonicotinamide and iron (II) sulphate heptahydrate were used as the reagent. The compound was synthesized by stirring under reflux. koordinacijska spojina ligand železo piridinkarboksamidi izonikotinamid rentgenska praškovna difrakcija Fourierjeva transformacijska infrardeča spektroskopija monokristalna analiza. coordination compound ligand iron pyridinecarboxamides isonicotinamid X-ray powder diffraction Fourier transform infrared spectroscopy single-crystal X-ray diffraction. true true false [N. Babič] Slovenski jezik Angleški jezik Magistrsko delo/naloga 2018-11-19 15:17:59 2018-12-13 12:48:58 2022-08-01 23:07:57 2019-07-11 19:31:36 2018 0 Maribor 0 0000-00-00 NiDoloceno NiDoloceno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 544.142.3:542(043.2) 24231688 URN:SI:UM:DK:WCTZEUZB MAG_Babic_Nejc_2018.pdf MAG_Babic_Nejc_2018.pdf 1 0972ADACB914B91BC859AB8C11611649 15d382b4956a3472caa352bfd8a7eb56b07165609f4ea1a1a750b96aab7caef8 8359d1a2-7c10-11eb-bb7a-00155d0001ca 20.500.12556/dkum/e5db7520-f24f-4590-8a4e-af54e4299b78 https://dk.um.si/Dokument.php?lang=slv&id=131528 Fakulteta za naravoslovje in matematiko 0 0 0