20.500.12556/DKUM-91764 Influence of crosslinker on the properties of terpene-based poly(high internal phase emulsion)s Poly(high internal phase emulsion)s (polyHIPEs) are an important class of porous polymeric materials, where HIPEs are used to create hierarchical open porosity. In order to synthesize more sustainable and greener polymer materials, bio-derived terpene-based polyHIPEs are becoming increasingly important. Herein, polyHIPEs were synthesized by free radical copolymerization crosslinking of β-myrcene with flexible poly(ethylene glycol dimethacrylate) or ethylene glycol dimethacrylate in water-in-oil HIPEs. The influence of using a flexible oligomeric crosslinker on pore morphology and mechanical properties of the resulting terpene-based polyHIPEs was investigated. Morphological and mechanical characterization of the terpene-based polyHIPEs reveals that using crosslinkers with varied flexibility significantly influences pore morphology and mechanical strength. In addition, altering the amount of crosslinker in the HIPE template has proved to be an important parameter in the final material properties. While the structure of the crosslinker has a less pronounced influence on the polyHIPE morphology, mechanical properties are significantly affected due to the difference in the resulting polymer architecture and free volume. © 2024 The Author(s). Polymer International published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry. terpene alpha-myrcene polyHIPE pore morphology mechanical properties terpeni polimeri morfologija por mehanske lastnosti true false true Wiley Angleški jezik Slovenski jezik https://scijournals.onlinelibrary.wiley.com/journal/10970126 © 2024 The Author(s) Članek v reviji 2025-02-03 14:21:12 2025-02-03 14:21:12 2026-01-15 10:05:55 0000-00-00 00:00:00 2024 0 0 7 str. First published: 07 November 2024 0000-00-00 Zaloznikova Objavljeno NiDoloceno 2024-08-01 2024-10-16 2024-11-07 66 215877635 10.1002/pi.6714 1097-0126 Polymer_International_-_2024_-_Beyaz_-_Influence_of_crosslinker_on_the_properties_of_terpene‐based_poly_high_internal_phase.pdf Polymer_International_-_2024_-_Beyaz_-_Influence_of_crosslinker_on_the_properties_of_terpene‐based_poly_high_internal_phase.pdf 1 EB7CA1982420A76384754B8B618F6923 675719538acf6599a332d3cf7b3653183e71f13081faaca60736a64657f65afd 27d4cae2-e232-11ef-9425-00155d000105 https://dk.um.si/Dokument.php?lang=slv&id=188410 https://scijournals.onlinelibrary.wiley.com/doi/10.1002/pi.6714 0 655eabeb-f1f1-11f0-9ca2-00155d580e02 https://dk.um.si/Dokument.php?lang=slv&id=202042 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0