20.500.12556/DKUM-94207 Myrcene-based porous polymers via emulsion templating and thiol-ene polymerization Porous polymer networks were synthesized via thiol-ene photo-polymerization using a naturally occurring terpene, myrcene and the multifunctional thiol, trimethylolpropane tris(3-mercaptopropionate). A highly porous structure (up to 80% porosity) was achieved by polymerizing the monomeric phase of high internal phase emulsions (HIPEs), composed of myrcene and trimethylolpropane tris(3-mercaptopropionate) in the presence of ethylene glycol dimethacrylate, which facilitated the formation of polyHIPE materials. Myrcene was incorporated in concentrations ranging from 9 to 40 mol%, and its content was found to significantly influence the resulting polymer morphology. Depending on the formulation, both bicontinuous-like and open-cell polyHIPE morphologies were obtained. In addition to myrcene content, the thiol-to-alkene functional group ratio (1:1 ratio of thiol to alkene groups, as well as formulations with an excess of alkene functionalities relative to thiols). photochemistry terpenes thiol-ene reaction polyHIPEs myrcene fotokemija terpeni mircen polimeri true false true Springer Angleški jezik Slovenski jezik https://link.springer.com/journal/706 © The Author(s) 2025 Članek v reviji 2025-08-08 10:40:02 2025-08-08 10:40:02 2025-08-09 03:20:03 0000-00-00 00:00:00 2025 0 0 7 str. Published: 04 August 2025 0000-00-00 Zaloznikova Objavljeno NiDoloceno 2025-04-26 2025-07-19 2025-08-04 66 245079299 10.1007/s00706-025-03360-2 1434-4475 s00706-025-03360-2.pdf s00706-025-03360-2.pdf 1 331C2668059956DA3C32F1DBD06D6C5E d5d724dee0a9c21360d244551bc1095c3fdab38fb6d64fd36feb321e54bcf97f 8bb9f6f7-7433-11f0-bafb-00155d000105 https://dk.um.si/Dokument.php?lang=slv&id=194943 Fakulteta za kemijo in kemijsko tehnologijo 0 0 0