| Title: | Localized dissolution kinetics of low carbon steel |
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| Authors: | ID Petek, Aljana (Author)
ID Doleček, Valter (Author) |
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| Files: |  Acta_Chimica_Slovenica_2007_Petek,_Dole_Localized_Dissolution_Kinetics_of_Low_Carbon_Steel.pdf (105,67 KB)
MD5: F09EF8CE830FA5C30119384D7966F039
PID: 20.500.12556/dkum/f2a55272-0b7d-4f1a-9d73-40413e37287e
 http://acta-arhiv.chem-soc.si/54/54-4-725.pdf
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| Language: | English |
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| Work type: | Scientific work |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: | FKKT - Faculty of Chemistry and Chemical Engineering
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| Abstract: | Localized dissolution of low carbon steel in saturated calcium hydroxide with different amount of sodium chloride has been investigated, using a dc technique. Potentiokinetic polarization curves indicated that pitting potentials ($E_{pit}$) decrease linearly with the log of chloride concentration. The rate of pit nucleation (1/$t_i$), and the rate of pits growth increases with increasing concentration of $Cl^-$ ions. Initiation of pitting attack could be ascribed to the adsorption of $Cl^-$ ions on the oxide surface. Adsorption of $Cl^-$ ions is physisorption and follow the Langmuir isotherm with $Δ_{ads}G^0$ = -21.1 kJ/mol. |
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| Keywords: | pitting corrosion, adsorption isotherm, low carbon steel, simulated interstitial solution |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Year of publishing: | 2007 |
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| Number of pages: | str. 725-729 |
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| Numbering: | Letn. 54, št. 4 |
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| PID: | 20.500.12556/DKUM-26033  |
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| ISSN: | 1318-0207 |
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| UDC: | 544.431 |
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| ISSN on article: | 1318-0207 |
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| COBISS.SI-ID: | 11991318 |
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| NUK URN: | URN:SI:UM:DK:TBXERCZT |
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| Publication date in DKUM: | 31.05.2012 |
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| Views: | 3008 |
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| Downloads: | 111 |
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| Metadata: |    |
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| Categories: | Misc.
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