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Title:Decolorization and mineralization of reactive dyes, by the $H_2O_2$/UV process with electrochemically produced $H_2O_2$
Authors:ID Jerič, Tina (Author)
ID Bisselink, Roel J. M. (Author)
ID Van Tongeren, Willy (Author)
ID Majcen Le Marechal, Alenka (Author)
Files:.pdf Acta_Chimica_Slovenica_2013_Jeric_et_al._Decolorization_and_Mineralization_of_Reactive_Dyes,_by_the_H2O2UV_Process_With_Electrochemicall.pdf (195,10 KB)
MD5: 902B6209846DD0FAF9A5300A42D295D2
 
URL http://acta-arhiv.chem-soc.si/60/60-3-666.pdf
 
Language:English
Work type:Scientific work
Typology:1.01 - Original Scientific Article
Organization:FS - Faculty of Mechanical Engineering
Abstract:Decolorization of Reactive Red 238, Reactive Orange 16, Reactive Black 5 and Reactive Blue 4 was studied in the UV/$H_2O_2$ process with $H_2O_2$ being produced electrochemically. The experimental results show that decolorization increased considerably when switching on the electrochemical production of $H_2O_2$. Complete decolorization (>99%) was achieved for all dyes under the applied experimental conditions, partial mineralization (49-85%) was obtained, which depends on the type of dye. Reactive Red 238 was used to investigate operational parameters and it was found that decolorization was influenced by the applied electrical current of the electrochemical cell and flow rate. Decolorization and mineralization of Reactive Red 238 can be described by pseudo-first order kinetics. It was found that the initial concentration of Reactive Red 238 has a negative influence on the pseudo-firstorder reaction constant.
Keywords:decolorization, hydrogen peroxide, reactive dyes, in-situ $H_2O_2$, AOP, Reactive Red 238
Publication status:Published
Publication version:Version of Record
Year of publishing:2013
Number of pages:str. 660-665
Numbering:Letn. 60, št. 3
PID:20.500.12556/DKUM-50471 New window
ISSN:1318-0207
UDC:543.544:677
ISSN on article:1318-0207
COBISS.SI-ID:17132566 New window
NUK URN:URN:SI:UM:DK:MR5T8PXL
Publication date in DKUM:10.07.2015
Views:1728
Downloads:88
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Acta Chimica Slovenica
Shortened title:Acta Chim. Slov.
Publisher:Slovensko kemijsko društvo
ISSN:1318-0207
COBISS.SI-ID:14086149 New window

Document is financed by a project

Funder:EC - European Commission
Funding programme:FP7
Project number:211534
Name:Water in Industry, Fit-for-Use Sustainable Water Use in Chemical, Paper, textile and Food Industry
Acronym:AQUAFIT4USE

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:10.07.2015

Secondary language

Language:Slovenian
Abstract:Z uporabo UV/$H_2O_2$ postopka, kjer smo $H_2O_2$ proizvedli elektrokemijsko, smo preučevali razbarvanje reaktivnih barvil Reactive Red 238, Reactive Orange 16, Reactive Black 5 in Reactive Blue 4. Iz eksperimentalnih rezultatov je razvidno, da se razbarvanje znatno poveča, ko vključimo elektrokemijsko proizvodnjo $H_2O_2$. Popolno razbarvanje vseh barvil (>99 %) smo dosegli pod uporabljenimi eksperimentalnimi pogoji, delna razgradnja (49-85 %) pa je bila odvisna od vrste barvila. Za ugotavljanje delovnih parametrov smo uporabili reaktivno barvilo Reactive Red 238. Na razbarvanje vplivajo: uporabljen električni tok ter hitrost pretoka. Razbarvanje in razgradnjo reaktivnega barvila Reactive Red 238 lahko opišemo z reakcijo psevdo-prvega reda, kjer ima začetna koncentracija barvila negativen vpliv na konstanto reakcije.
Keywords:tekstilne odpadne vode, reaktivna barvila, razbarvanje, vodikov peroksid


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