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Title:SINTEZE KOORDINACIJSKIH SPOJIN BAKRA S TIO-LIGANDI IN PRIPRAVA BAKROVIH SULFIDOV Z NJIHOVIM KONTROLIRANIM TERMIČNIM RAZKROJEM
Authors:ID Radić, Tanja (Author)
ID Kristl, Matjaž (Mentor) More about this mentor... New window
ID Ban, Irena (Comentor)
Files:.pdf MAG_Radic_Tanja_2015.pdf (3,09 MB)
MD5: 32C60C398FA431597E82CE35F681784F
 
Language:Slovenian
Work type:Master's thesis/paper
Typology:2.09 - Master's Thesis
Organization:FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:Namen magistrskega dela je bila sinteza koordinacijskih spojin bakra s tio-ligandi, saj baker in žveplo tvorita veliko različnih spojin. Kot vir bakra smo uporabili baker (v prahu), bakrov(II) acetat monohidrat, bakrov(II) klorid dihidrat in bazični bakrov(II) karbonat. Kot ligande smo uporabili 2-aminobenzotiazol, 2,2-ditiobis(benzotiazol) in tioureo. Izvajali smo reakcije med viri bakra in viri žvepla v različnih topilih in z dvema različnima metodama (refluks in mešanje). Kot topila smo uporabili destilirano vodo, dimetilformamid in metanol. Reakcije so potekale pri sobni temperaturi (metoda mešanja) in pri povišani temperaturi (upoštevajoč temperature vrelišča posameznega topila) na oljni kopeli (t.i. metoda refluksa). Produkte smo okarakterizirali z rentgensko praškovno difrakcijo (XRD) in termogravimetrično analizo.
Keywords:baker, tio-ligandi, bakrovi sulfidi, termoliza molekularnih prekurzorjev, rentgenska praškovna difrakcija (XRD), termogravimetrična analiza, koordinacijske spojine
Place of publishing:Maribor
Publisher:[T. Radić]
Year of publishing:2015
PID:20.500.12556/DKUM-55648 New window
UDC:549.332:544.016.2(043.2)
COBISS.SI-ID:19446038 New window
NUK URN:URN:SI:UM:DK:WZIXQF3K
Publication date in DKUM:24.12.2015
Views:2621
Downloads:290
Metadata:XML DC-XML DC-RDF
Categories:KTFMB - FKKT
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Secondary language

Language:English
Title:SYNTHESIS OF COPPER COORDINATION COMPOUNDS WITH SULFUR-CONTAINING LIGANDS AND PREPARATION OF COPPER SULFIDES BY THEIR CONTROLLED THERMAL DECOMPOSITION
Abstract:The purpose of the master work was the synthesis of coordination compounds of copper with thioligands as copper and sulfur form a large variety of compounds. As the source of copper was used copper (powder), copper(II) acetate monohydrate, copper(II) chloride dihydrate, and basic copper(II) carbonate. Following sulfur containing ligands were used: 2- aminobenzothiazole, 2,2- dithiobis(benzothiazole) and thiourea. We carried out the reaction between the copper resources and thioligands in different solvents and by two different methods (reflux and stirring). We have used distilled water, dimethylformamide and methanol as solvents. The reactions were carried out under room temperature and at elevated temperature (taking into account the boiling point of each solvent) in an oil bath (so-called method of the reflux). The products were characterized by X-ray powder diffraction (XRD) and thermogravimetric analysis.
Keywords:copper, thioligands, copper sulphides, thermolysis of molecular precursors, X-ray powder diffraction (XRD), thermogravimetric analysis, coordination compounds.


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