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Title:Vpliv razmerja tiol/alken na lastnosti polimernih membran
Authors:ID Črešnar, Blažka (Author)
ID Krajnc, Peter (Mentor) More about this mentor... New window
ID Paljevac, Muzafera (Comentor)
Files:.pdf UN_Cresnar_Blazka_2016.pdf (2,50 MB)
MD5: EA01D2BEF1E39733A6600B56700314CC
 
Language:Slovenian
Work type:Undergraduate thesis
Typology:2.11 - Undergraduate Thesis
Organization:FNM - Faculty of Natural Sciences and Mathematics
Abstract:Namen diplomske naloge je bil pripraviti porozne polimerne membrane iz pentaeritritol tetrakis(3-merkaptopropionata) in trimetilolpropan triakrilata ter trimetilolpropan triakrilata in divinil adipata. Membrane smo pripravili tako, da smo fotopolimerizirali kontinuirno fazo emulzije z visokim deležem interne faze (HIP emulzije), kjer kontinuirno fazo predstavlja monomerna mešanica, interno fazo pa vodna raztopina kalcijevega heksahidrata. HIP emulzijo smo pri uporabi pentaeritritol tetrakis(3-merkaptopropionata) stabilizirali s surfaktantom Pluronic, pri uporabi trimetilolpropan triakrilata pa s surfaktantom Span 65. Stabilno HIP emulzijo z določeno kemijsko sestavo smo nato s pomočjo posebnih »nožev« različnih debelin nanesli na stekleno ploščo in v UV-komori izvedli polimerizacijo. Nastale so porozne poliHIPE membrane z debelinami 300–1000 μm. Z infrardečo spektroskopijo smo preverili kemijsko sestavo membran, z vrstičnim elektronskim mikroskopom pa morfologijo sintetiziranih membran.
Keywords:Radikalska polimerizacija, tiol-en reakcija, membrane, emulzija z visokim deležem interne faze (HIP emulzija), tetratiol, divinil adipat, trimetilolpropan triakrilat
Place of publishing:Maribor
Publisher:[B. Črešnar]
Year of publishing:2016
PID:20.500.12556/DKUM-60674 New window
UDC:544.725(043.2)
COBISS.SI-ID:22579720 New window
NUK URN:URN:SI:UM:DK:YBRBDEZR
Publication date in DKUM:26.09.2016
Views:1830
Downloads:138
Metadata:XML DC-XML DC-RDF
Categories:FNM
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Secondary language

Language:English
Title:The influence of thiol/alkene ratio on the properties of polymeric membranes,
Abstract:The purpose of the graduation thesis was to prepare porous polymeric membranes from pentaerythritol tetrakis(3-mercaptopropionate) and trimethylolpropane triacrylate; trimethylolpropane triacrylate and divinyl adipate. We prepared membranes by photopolymerisation of the continuous phase of a high internal phase emulsion (HIP emulsion), where the continuous phase is represented by the monomer mixture and the internal phase by the aqueous solution of calcium hexahydrate. In the case of pentaerythritol tetrakis(3-mercaptopropionate), HIP emulsion was stabilised with the surfactant Pluronic, and in the case of trimethylolpropane triacrylate with the surfactant Span 65. Afterwards, we applied stable HIP emulsion with a specific chemical composition on a glass plate using special “knives” of different thicknesses and performed polymerisation in UV chamber. PolyHIPE porous membranes with thicknesses of 300-1000 micrometers were formed. By using infrared spectroscopy, we checked the chemical structure of membranes, and by using scanning electron microscope, we checked the morphology of the synthesized membranes.
Keywords:Radical polymerisation, thiol-ene reaction, membranes, high internal phase emulsion (HIP emulsion), tetrathiol, divinyl adipate, trimethylolpropane triacrylate


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