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Title:
Synthesis and structure of transition metal bisalkinylselenolato complexes
Authors:
ID
Pietschnig, Rudolf
(
Author
)
ID
Moser, Carmen
(
Author
)
ID
Spirk, Stefan
(
Author
)
ID
Schäfer, Sven
(
Author
)
Files:
Molecules_2005_Pietschnig_et_al._Synthesis_and_structure_of_transition_metal_bisalkinylselenolato_complexes.pdf
(614,73 KB)
MD5: 543BA12C0F8E37CD9518363233835273
http://www.usc.es/congresos/ecsoc/9/ECSOC9.HTM
Language:
English
Work type:
Scientific work
Typology:
1.08 - Published Scientific Conference Contribution
Organization:
FS - Faculty of Mechanical Engineering
Abstract:
We synthesized closely related cis and trans platinum complexes of SeCC-n-C5H11 and elucidated their structures in solution and the crystalline state. In line with previous work we find exclusive coordination of the selenium atom of the ambident alkynylselenolate ligand and a preference for the obviously more stable trans isomer. In contrast to previous work we find auniform increase of all metal ligand bond lengths in the cis vs. the trans isomers. Moreover we studied the coordination of alkynykselenolate ligands to group 4 metals.
Keywords:
analytical chemistry
,
isomers
,
stability
,
metals
Publication status:
Published
Publication version:
Version of Record
Year of publishing:
2005
Number of pages:
str. 1-9
PID:
20.500.12556/DKUM-66357
ISSN:
1420-3049
UDC:
543.632.585
ISSN on article:
1420-3049
COBISS.SI-ID:
68800257
NUK URN:
URN:SI:UM:DK:PQFSHUWE
Publication date in DKUM:
22.06.2017
Views:
1389
Downloads:
381
Metadata:
Categories:
Misc.
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Record is a part of a proceedings
Title:
Proceedings of ECSOC-9, the Ninth International Electronic Conference on Synthetic Organic Chemistry
COBISS.SI-ID:
68799745
Record is a part of a journal
Title:
Molecules
Shortened title:
Molecules
Publisher:
MDPI
ISSN:
1420-3049
COBISS.SI-ID:
18462981
Licences
License:
CC BY 4.0, Creative Commons Attribution 4.0 International
Link:
http://creativecommons.org/licenses/by/4.0/
Description:
This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:
22.06.2017
Secondary language
Language:
Slovenian
Keywords:
analizna kemija
,
izomeri
,
stabilnost
,
kovine
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