| Title: | The crystal and molecular structures of two reaction products of geminal dicyano oxirane with thiohydantoine (compound I) and thioxobenzoxazole (compound II) |
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| Authors: | ID Leban, Ivan (Author)
ID Majcen Le Marechal, Alenka (Author)
ID Robert, Albert (Author) |
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| Files: |  Croatica_Chemica_Acta_1993_Leban,_Majcen_Le_Marechal,_Robert_The_crystal_and_molecular_structures_of_two_reaction_products_of_geminal_di.pdf (16,17 MB)
MD5: 4091A3ECE2CAA1326CD6A8C88370DDF9
PID: 20.500.12556/dkum/85ffd4a3-946f-4159-9175-a5ec5798e440
 http://hrcak.srce.hr/137072
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| Language: | English |
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| Work type: | Scientific work |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: | FS - Faculty of Mechanical Engineering
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| Abstract: | The crystal and molecular structures of two reaction products of geminal dicyano oxiranes with thiohydantoione and thioxobenzoxazole have been determinated from ▫$Mo-K_\alpha$▫ X-ray diffraction data. The two reaction products were: 2H-2-(p-tolyl)-imidazol[1,2-b]thiazole-3,6-dione (compound I) and Z-3-benzoxazole-3-phenyl-2-oxo-2-propanenitrile (compound II) with the following crystal data at 293(1) K: Compound I, ▫$C_{12}H_{10}N_2O_2S$▫, monoclinic ▫$P2_1/c$▫, a=15057(3), b=5.200(3), c=14.724(4) Å, ▫$\beta=104.24(3)°$▫, Z=4; final R and ▫$R_w$▫ values were 0.034 and 0.049 for1647 observed reflexions. Compound II, ▫$C_{16}H{10}N_2O_2$▫, monoclinic, ▫$P2_1/n$▫, a=14.396(3), b=4.326(1), c=21.335(4) Å, ▫$\beta-107.79(1)°$▫, Z=4;final R and ▫$R_w$▫ values 0.040 and 0.053 for 1516 observed reflections. |
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| Keywords: | organic chemistry, crystal structure, chemical reactions, oxiranes, coordination compounds, structural chemistry |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Year of publishing: | 1993 |
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| Number of pages: | str. 393-400 |
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| Numbering: | Letn. 66, št. 2 |
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| PID: | 20.500.12556/DKUM-66670  |
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| ISSN: | 0011-1643 |
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| UDC: | 538.911:547-311 |
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| ISSN on article: | 0011-1643 |
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| COBISS.SI-ID: | 17906437 |
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| NUK URN: | URN:SI:UM:DK:9LNXUSFG |
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| Publication date in DKUM: | 05.07.2017 |
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| Views: | 1787 |
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| Downloads: | 126 |
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| Metadata: |    |
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| Categories: | Misc.
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