| Title: | Two new zinc(II) acetates with 3- and 4-aminopyridine : syntheses and structural properties |
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| Authors: | ID Dojer, Brina (Author)
ID Pevec, Andrej (Author)
ID Belaj, Ferdinand (Author)
ID Kristl, Matjaž (Author) |
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| Files: |  Acta_Chimica_Slovenica_2015_Dojer_et_al._Two_new_zinc(II)_acetates_with_3–_and_4–aminopyridine_syntheses_and_structural_properties.pdf (1,06 MB)
MD5: 199B2781D152364626CE89E102A1271C
PID: 20.500.12556/dkum/8cd9754e-08a7-48c0-aec8-3a0cea5ebf98
 https://journals.matheo.si/index.php/ACSi/article/view/1111
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| Language: | English |
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| Work type: | Article |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: | FNM - Faculty of Natural Sciences and Mathematics
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| Abstract: | The synthesis and characterization of two new zinc(II) coordination compounds with 3- and 4-aminopyridine are reported. They were obtained after adding a water solution of $Zn(CH_3COO)_2$ · $2H_2O$ or dissolving solid $Zn(CH_3COO)_2$ · $2H_2O$ in methanol solutions of 3- and 4-aminopyridine. The products were characterized structurally by single-crystal X-ray diffraction analysis. Colourless crystals of the compound synthesized by the reaction of $Zn(CH_3COO)_2$ · $2H_2O$ and 3-aminopyridine (3-apy), are built of trinuclear complex molecules with the formula $[Zn_3(O_2CCH_3)_6(3- apy)_2(H_2O)_2]$(1). The molecules consists of two terminal $Zn$ atoms, coordinated tetrahedrally, and one central $Zn$ atom, coordinated octahedrally. Colourless crystals, obtained by the reaction of $Zn(CH_3COO)_2$ · $2H_2O$ with 4-aminopyridine (4-apy), consist of a mononuclear complex $[Zn(O_2CCH_3)_2(4-apy)_2]$(2). Hydrogen-bonding interactions in the crystal structures of both complexes are reported. |
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| Keywords: | zinc(II) acetate dihydrate, aminopyridine, x-ray crystal structure, hydrogen bonds |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Year of publishing: | 2015 |
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| Number of pages: | str. 312-318 |
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| Numbering: | Letn. 62, št. 2 |
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| PID: | 20.500.12556/DKUM-67759  |
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| ISSN: | 1318-0207 |
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| UDC: | 546.47:547.82 |
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| ISSN on article: | 1318-0207 |
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| COBISS.SI-ID: | 1536350147 |
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| DOI: | 10.17344/acsi.2014.1111 |
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| NUK URN: | URN:SI:UM:DK:72RRPCZP |
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| Publication date in DKUM: | 30.08.2017 |
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| Views: | 2208 |
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| Downloads: | 167 |
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| Metadata: |    |
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| Categories: | Misc.
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