Reakcije metilaminov z vodikovimi halogenidi in njihova uporaba v sintezi koordinacijskih spojin : magistrsko delo

Siher, Anja

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Title:	Reakcije metilaminov z vodikovimi halogenidi in njihova uporaba v sintezi koordinacijskih spojin : magistrsko delo
Authors:	ID Siher, Anja (Author) ID Kristl, Matjaž (Mentor) More about this mentor... ID Ban, Irena (Comentor)
Files:	MAG_Siher_Anja_2021.pdf (2,58 MB) MD5: 8A457A82FFC2E4E3E8F6DD4A6397C1C9 PID: 20.500.12556/dkum/8103cd5a-e981-41b7-9d8c-dd5bb20f9fae
Language:	Slovenian
Work type:	Master's thesis/paper
Typology:	2.09 - Master's Thesis
Organization:	FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:	V magistrskem delu smo raziskovali derivate amonijaka, in sicer metilamine (dimetilamine, trimetilamine in tetrametilamine) ter njihove koordinacijske spojine. Predpostavili smo, da bodo metilamini (dimetilamini, trimetilamini in tetrametilamini) tvorili trdne produkte z vodikovimi halogenidi, kjer smo izbrali halogeni element klor. Reaktante smo sintetizirali z reakcijo nevtralizacije pri sobni temperaturi ter s segrevanjem na vodni kopeli. Reakcija med metilaminom ter klorovodikovo kislino je bila uspešna, tako da smo dobljeni produkt metilamonijev klorid karakterizirali ter potrdili z rentgensko monokristalno analizo. Ostali produkti reakcij so bili neobstojni, tako da smo jih označili za neuspešne sinteze. Glede na to, da se metilamini (dimetilamini in trimetilamini) obnašajo podobno kot amonijak, smo jih uporabili pri tvorbi koordinacijskih spojin. Za centralni atom smo izbrali baker, ki smo ga dodajali v obliki bakrovih(II) spojin (CuSO4·5H2O, Cu(CH3COO)2,Cu(CH3COO)2·H2O ter CuCl2). Sinteze koordinacijskih spojin so potekale pri različnih množinskih razmerjih (1:1, 2:1 ter 4:1) in različnih topilih (metanol, etanol, destilirana voda ter acetonitril). Sinteze reaktantov smo izvedli z mešanjem pri sobni temperaturi ter z reakcijo na refluksu. Za karakterizacijo nastalih kristalov smo uporabili termogravimetrično metodo (TGA) in monokristalno rentgensko analizo. Uspešno smo sintetizirali štiri nove spojine, katerim smo določili pripadajočo strukturo ter jih opisali. Ostali analizirani vzorci so se izkazali za že znane spojine, katerih strukture so karakterizirane ter opisane v člankih.
Keywords:	metilamonijev klorid, bakrove(II) spojine, vodikovi halogenidi, koordinacijske spojine, termogravimetrična metoda (TGA), rentgenska analiza na monokristalu
Place of publishing:	Maribor
Place of performance:	Maribor
Publisher:	[A. Siher]
Year of publishing:	2021
Number of pages:	XII, 69 f.
PID:	20.500.12556/DKUM-78991
UDC:	547.43:544.146.3.057(043.2)
COBISS.SI-ID:	61713155
Publication date in DKUM:	03.05.2021
Views:	1979
Downloads:	127
Metadata:
Categories:	KTFMB - FKKT
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Licences

License:	CC BY 4.0, Creative Commons Attribution 4.0 International

Link:	http://creativecommons.org/licenses/by/4.0/
Description:	This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:	12.04.2021

Secondary language

Language:	English
Title:	Reactions of methylamines with hydrogen halogenides and their applications in the synthesis of coordination compounds
Abstract:	In this master thesis ammonia derivatives, namely methylamine (dimethylamine, trimethylamine and tetramethylamine) and their coordination compounds were investigated. We assumed that methylamines (dimethylamines, trimethylamines and tetramethylamines) will form solid products with hydrogen halide, where the selected halide element was chlorine. Neutralization reaction with elevated temperature and at room temperature was used to synthesize the reactants. Reaction between methylamine and hydrogen chloride was successful, and the obtained product methylammonium chloride was characterised and confirmed with single crystal X-ray diffraction analysis. Other products of reactions were unstable and unsuccessful. Considering that methylamines (dimethylamines and trimethylamines) behave similar to ammonia, we used them to form coordination compounds. Copper was used as the central atom and added as copper(II) compounds (CuSO4·5H2O, Cu(CH3COO)2,Cu(CH3COO)2·H2O and CuCl2). For the synthesis of coordination compounds, we used different molar ratios (1:1, 2:1 and 4:1) and solvents (distilled water, ethanol, methanol and acetonitrile). We synthesized reactants with stirring at room temperature and with reaction of reflux. Formed crystals were characterised with thermogravimetric analysis (TGA) and single crystal X-ray diffraction analysis. We successfully synthesised four new compounds, to which we determined corresponding structure. Other analysed samples were already known compounds, which we can find characterised and described in different articles.
Keywords:	methylammonium chloride, copper(II) compounds, hydrogen halide, coordination compounds, thermogravimetric analysis, single crystal X-ray diffraction analysis

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