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Title:Assessment of the Capability of Magnetic Nanoparticles to Recover Neodymium Ions from Aqueous Solution
Authors:ID Ambrož, Ana (Author)
ID Ban, Irena (Author)
ID Luxbacher, Thomas (Author)
Files:.pdf Assessment_of_the_Capability_of_Ma-Ambroz-2022.pdf (829,86 KB)
MD5: E19965ADF6868FA92825CEBE20DE0468
 
URL https://acsi-journal.eu/index.php/ACSi/article/view/7570/3584
 
Language:English
Work type:Article
Typology:1.01 - Original Scientific Article
Organization:FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:Magnetic nanoparticles (MNPs) have received increasing attention for various applications due to their fast synthesis, versatile functionalization, and recyclability by the application of a magnetic field. The high surface-to-volume ratio of MNP dispersions has suggested their use as an adsorbent for the removal of heavy metal ions. We investigated the applicability of MNPs composed of a maghemite core surrounded by a silica shell functionalized with aminopropylsilane, γ-Fe2O3-NH4OH@SiO2(APTMS), for the removal of neodymium ions (Nd3+) from aqueous solution. The MNPs were characterized for their size, composition, surface functionality and charge. Despite of the promising properties of MNPs, their removal from the aqueous dispersion with an external magnet was not sufficient to reliably quantify the adsorption of Nd3+ by UV-Vis spectroscopy.
Keywords:rare earth elements, maghemite, nanoparticles, UV-Vis spectroscopy, adsorption
Publication status:Published
Publication version:Version of Record
Submitted for review:10.03.2022
Publication date:15.12.2022
Publisher:Slovensko kemijsko društvo (Slovenian Chemical Society)
Year of publishing:2022
Number of pages:str. 826-836
Numbering:Vol. 69
PID:20.500.12556/DKUM-84918 New window
UDC:620.3
ISSN on article:1580-3155
COBISS.SI-ID:160368643 New window
DOI:10.17344/acsi.2022.7570 New window
Publication date in DKUM:08.08.2023
Views:662
Downloads:287
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Acta chimica slovenica
Shortened title:Acta chim. slov.
Publisher:Slovensko kemijsko društvo (Slovenian Chemical Society)
ISSN:1580-3155
COBISS.SI-ID:21870085 New window

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Abstract:Magnetni nanodelci (MNP) so zaradi svoje hitre sinteze, vsestranske funkcionalizacije in možnosti recikliranja z uporabo magnetnega polja deležni vse večje pozornosti za različne aplikacije. Visoko razmerje med površino in prostornino disperzij MNP predstavlja zmožnost njihove uporabe kot adsorbenta za odstranjevanje ionov težkih kovin. Raziskali smo uporabnost MNP, sestavljenih iz maghemitnega jedra in obdanih s kremenčevo lupino, funkcionalizirano z aminopropilsilanom, γ-Fe2O3-NH4OH@SiO2 (APTMS), za odstranjevanje neodimovih ionov (Nd3+) iz vodne raztopine. MNP so bili karakterizirani glede na velikost, sestavo, površinsko funkcionalnost in naboj. Kljub obetavnim lastnostim MNP pa njihova odstranitev iz vodne disperzije z zunanjim magnetom ni zadostovala za zanesljivo kvantificiranje adsorpcije Nd3+ z UV-Vis spektroskopijo.
Keywords:redki elementi zemlje, nanodelci, spektroskopija, adsorpcija


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