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Title:Chemical decomposition of thermosets : diplomsko delo
Authors:ID Handjiski, Vasil (Author)
ID Volmajer Valh, Julija (Mentor) More about this mentor... New window
ID Leitner, Johannes (Comentor)
Files:.pdf Diplomska_naloga_Vasil_Handjiski_nova.pdf (3,55 MB, This file will be accessible after 21.08.2027)
MD5: B0873F42D45B4EB760BB7A83EBBA94A6
 
Language:English
Work type:Bachelor thesis/paper
Typology:2.11 - Undergraduate Thesis
Organization:FS - Faculty of Mechanical Engineering
Abstract:This bachelor thesis depicts the chemical degradation of polyurethane and melamine formaldehyde, which are representatives of thermosets. A high–pressure reactor was used to perform chemical degradation. The effectiveness of the chemical degradation of the selected thermosets was monitored by measuring pH, total organic carbon (TOC) and total nitrogen (TN) of the liquid residues. The remaining solid material was characterized by infrared spectroscopy and the mass loss was determined. Using these analytical methods, it was concluded that the chemical degradation depends on the temperature and the duration of the reactions as well as the reaction medium. It was found that “white liquor” is a more effective medium for the chemical degradation of polyurethane and melamine formaldehyde than water.
Keywords:chemical degradation, polyurethane, melamine formaldehyde, FTIR
Place of publishing:Maribor
Place of performance:Maribor
Publisher:[V. Handjiski]
Year of publishing:2024
Number of pages:1 spletni vir (1 datoteka PDF (XV, 70 f.))
PID:20.500.12556/DKUM-89784 New window
UDC:66.092:678.6(043.2)
COBISS.SI-ID:255231491 New window
Publication date in DKUM:22.10.2024
Views:124
Downloads:0
Metadata:XML DC-XML DC-RDF
Categories:KTFMB - FS
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Licences

License:CC BY-NC 4.0, Creative Commons Attribution-NonCommercial 4.0 International
Link:http://creativecommons.org/licenses/by-nc/4.0/
Description:A creative commons license that bans commercial use, but the users don’t have to license their derivative works on the same terms.
Licensing start date:16.08.2024

Secondary language

Language:Slovenian
Title:Kemijska razgradnja termosetov
Abstract:Diplomsko delo prikazuje kemijsko razgradnjo poliuretana in melamin formaldehida, ki sta predstavnika termosetov. Za izvedbo potrebne kemijske razgradnje je bil uporabljen visokotlačni reaktor. Učinkovitost kemijske razgradnje izbranih termosetov smo spremljali z meritvijo pH vrednosti, vrednosti celokupnega organskega ogljika (TOC) in celokupnega dušika (TN) tekočega ostanka. Preostel trden materialu smo okarakterizirali z infrardečo spektroskopijo in določili izgubo mase. Z uporabo teh analiznih metod je bilo ugotovljeno, da je kemijska razgradnja odvisna od temperature in časa reakcije ter reakcijksega medija. Izkazalo se je, da je ,”white liquor” bolj učinkovit medij pri kemijski razgradnji poliuretana in melamin formaldehida kot voda.
Keywords:kemijska razgradnja, poliuratan, melamin formaldehid, FTIR


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