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Title:Periodic arrays of chiral domains generated from the self-assembly of micropatterned achiral lyotropic chromonic liquid crystal
Authors:ID Park, Geonhyeong (Author)
ID Čopar, Simon (Author)
ID Suh, Ahram (Author)
ID Yang, Minyong (Author)
ID Tkalec, Uroš (Author)
ID Yoon, Dong Ki (Author)
Files:.pdf Park-2020-Periodic_Arrays_of_Chiral_Domains_Ge.pdf (11,64 MB)
MD5: AE074BF857EE2E57D9B0A79BD2948552
 
URL https://doi.org/10.1021/acscentsci.0c00995
 
Language:English
Work type:Scientific work
Typology:1.01 - Original Scientific Article
Organization:FNM - Faculty of Natural Sciences and Mathematics
Abstract:Achiral building blocks forming achiral structures is a common occurrence in nature, while chirality emerging spontaneously from an achiral system is usually associated with important scientific phenomena. We report on the spontaneous chiral symmetry-breaking phenomena upon the topographic confinement of achiral lyotropic chromonic liquid crystals in periodically arranged micrometer scale air pillars. The anisotropic fluid arranges into chiral domains that depend on the arrangement and spacing of the pillars. We characterize the resulting domains by polarized optical microscopy, support their reconstruction by numerical calculations, and extend the findings with experiments, which include chiral dopants. Well-controlled and addressed chiral structures will be useful in potential applications like programmable scaffolds for living liquid crystals and as sensors for detecting chirality at the molecular level.
Keywords:physical chemistry, atmospheric chemistry, chromatography, deformation, silicon, symmetry breaking, chiral domains, liquid crystal
Publication status:Published
Publication version:Version of Record
Submitted for review:28.07.2020
Publication date:09.09.2020
Publisher:ACS Publications
Year of publishing:2020
Number of pages:Str. 1964-1970
Numbering:Letn. 6, št. 11
PID:20.500.12556/DKUM-92381 New window
UDC:544
ISSN on article:2374-7951
COBISS.SI-ID:28153859 New window
DOI:10.1021/acscentsci.0c00995 New window
Publication date in DKUM:03.04.2025
Views:144
Downloads:4
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:ACS central science
Shortened title:ACS cent. sci.
Publisher:ACS Publications
ISSN:2374-7951
COBISS.SI-ID:525845529 New window

Document is financed by a project

Funder:ARRS - Slovenian Research Agency
Project number:P1-0099
Name:Fizika mehkih snovi, površin in nanostruktur

Funder:ARRS - Slovenian Research Agency
Project number:P1-0055
Name:Biofizika polimerov, membran, gelov, koloidov in celic

Funder:NRF - National Research Foundation of Korea
Project number:2017R1E1A1A01072798

Funder:NRF - National Research Foundation of Korea
Project number:2018R1A5A1025208

Funder:NRF - National Research Foundation of Korea
Project number:2019K1A3A1A14065772

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:09.09.2020

Secondary language

Language:Slovenian
Keywords:fizikalna kemija, atmosferska kemija, kromatografija, deformacija, silicij, razbijanje simetrije, kiralne domene, tekoči kristali


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