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Title:Upcycling of plastic waste into multi-walled carbon nanotubes as efficient organic dye adsorbent
Authors:ID Gaceva, Gordana Bogoeva (Author)
ID Sokolovska, Meri (Author)
ID Stefov, Viktor (Author)
ID Najdoski, Metodija (Author)
ID Kovačič, Sebastijan (Author)
Files:.pdf 16+SP+9145-01-08-25.pdf (1,09 MB)
MD5: 0FADA0D92F30C5187E9491E2201D727B
 
URL https://acsi-journal.eu/index.php/ACSi/article/view/9145
 
URL https://acsi-journal.eu/index.php/ACSi/article/view/9145/10230
 
Language:English
Work type:Article
Typology:1.01 - Original Scientific Article
Organization:FKKT - Faculty of Chemistry and Chemical Engineering
Abstract:Multi-walled CNTs with an average diameter of about 80 nm, a length of several micrometers and surface area (SBET) of 100 m2 g–1 were obtained by pyrolysis of low-density polyethylene waste. The potential of the resulting MWCNTs material to purify water containing organic dyes was tested with Bezaktiv Blau HE-RM (BB) and Bezaktiv Rot S-3B (BR) reactive dyes. 200 mg L–1 MWCNT material was used to follow the adsorption of 30 mg L–1, 40 mg L–1, 50 mg L–1 and 60 mg L–1 BB and BR at pH 3 and a temperature of ~25 °C. The results have shown that this material has a high potential as a sorbent, and its adsorption capacity of 257 mg g–1 (for Bezaktiv BlauHE-RM) and 213 mg g–1 (for Bezaktiv Rot) is close to some commercial MWCNTs and functionalized MWCNT-based adsorbents. The adsorption process was very fast, reaching 80–90% of the dye removal in 10–15 minutes, and the equilibrium time was reached in 40–60 minutes. The adsorption isotherm showed that the Langmuir model was more suitable than the Freundlich model for describing the adsorption properties of the pollutants.
Keywords:adsorption, anionic dyes, upcycling plastic waste, carbon nanotubes
Publication status:Published
Publication version:Version of Record
Submitted for review:08.01.2025
Publication date:03.03.2025
Publisher:Slovensko kemijsko društvo (Slovenian Chemical Society)
Year of publishing:2025
Number of pages:str. 154-163
Numbering:let. 72, št. 1
PID:20.500.12556/DKUM-95212 New window
UDC:54
ISSN on article:1580-3155
COBISS.SI-ID:229767171 New window
DOI:10.17344/acsi.2025.9145 New window
Copyright:Copyright (c) 2025 Gordana Bogoeva-Gaceva, Meri Sokolovska, Viktor Stefov, Metodija Najdoski, Sebastijan Kovačič
Publication date in DKUM:12.01.2026
Views:124
Downloads:2
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Acta chimica slovenica
Shortened title:Acta chim. slov.
Publisher:Slovensko kemijsko društvo (Slovenian Chemical Society)
ISSN:1580-3155
COBISS.SI-ID:21870085 New window

Document is financed by a project

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P2-0150
Name:Integralni pristop k preprečevanju onesnaževanja voda

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Keywords:adsorpcija, anionska barvila, recikliranje plastičnih odpadkov, karbonske nanocevke


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