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Title:Changes in Internal Resistance of Lithium-Sulfur Batteries When Using Electrolytes Based on Ionic Liquid [Deme][Tfsi], Sulfolane or Tegdme Solvent
Authors:ID Drvarič Talian, Sara (Author)
ID Dominko, Robert (Author)
Files:.pdf Changes_in_internal_resist-Drvaric_Talian-2022.pdf (402,17 KB)
MD5: 919075570A6E17B1E64972C6B600EF73
 
URL https://journals.um.si/index.php/anali-pazu/article/view/1918
 
Language:English
Work type:Scientific work
Typology:1.01 - Original Scientific Article
Organization:UZUM - University of Maribor Press
Abstract:Internal resistance of lithium-sulfur batteries was investigated with impedance spectroscopy. In order to understand the effect of various common solvents for Li-S battery preparation, the electrolyte in the cells was varied (ionic liquid [DEME][TFSI], sulfolane or TEGDME solvent). The impedance changes were followed at several points during discharge and charge of the batteries and through 50 cycles of their use. The resulting spectra were analyzed and fitted, extracting information on four different impedance contribution. The contributions were assigned to the electrolyte, anode or cathode. Their change through a single cycle and through multiples cycles of battery use was evaluated as well as compared between cells employing different electrolytes.
Keywords:lithium-sulfur batteries, polysulfides, impedance spectroscopy, ionic liquid, electrolytes
Publication status:Published
Publication version:Version of Record
Publication date:01.01.2021
Place of publishing:Maribor
Publisher:Univerza v Mariboru, Univerzitetna založba
Year of publishing:2021
Number of pages:5
Numbering:Letn.11, št.1/2
PID:20.500.12556/DKUM-97276 New window
UDC:544.5/.6
ISSN on article:2820-364X
COBISS.SI-ID:87617539 New window
DOI:10.18690/analipazu.11.1-2.64-71.2021 New window
Publication date in DKUM:26.02.2026
Views:212
Downloads:6
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Anali PAZU
Publisher:Združenje Pomurska akademsko znanstvena unija, Združenje Pomurska akademsko znanstvena unija, Univerzitetna založba Univerze v Mariboru
ISSN:2232-416X
COBISS.SI-ID:257553152 New window

Document is financed by a project

Funder:EC - European Commission
Funding programme:H2020
Project number:666221
Name:High energy lithium sulphur cells and batteries
Acronym:HELIS

Licences

License:CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Link:http://creativecommons.org/licenses/by-nc-nd/4.0/
Description:The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.

Secondary language

Language:Slovenian
Title:Spremembe notranje odpornosti litij-žveplovih baterij pri uporabi elektrolitov na osnovi ionske tekočine [DEME] [TFSI], sulfolana ali topila TEGDME
Abstract:Tehnika impedančne spektroskopije je bila uporabljena za študijo notranje upornosti litijžveplovih akumulatorjev. Da bi razumeli vpliv različnih topil pogosto uporabljanih v elektrolitih za Li-S akumulatorje, so bili v raziskavi uporabljeni trije različni elektroliti (na osnovi ionske tekočine [DEME] [TFSI], topila sulfolan, ali topila TEGDME). Spremembe v notranji upornosti smo spremljali na več točkah praznjenja in polnjenja celic ter čez 50 ciklov delovanja. Iz impedančnih spektrov so bili preko analize in prileganja z enostavnim ekvivalentnim vezjem razločeni štirje impedančni prispevki, ki so bili pripisani elektrolitu, procesom na anodi ali procesom na katodi. Narejena je bila analiza sprememb v velikostih teh prispevkov in primerjava med različnimi uporabljenimi elektroliti.
Keywords:litij-žveplovi akumulatorji, impedančna spektroskopija, polisulfidi, ionska tekočina, elektroliti


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  1. Anali PAZU

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