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Title:Water droplet attraction and coalescence on liquid-crystal-infused textured and porous surfaces
Authors:ID Ferš, Filip (Author)
ID Wang, Xiaoguang (Author)
ID Tkalec, Uroš (Author)
Files:.pdf RAZ_Fers_Filip_2026.pdf (3,38 MB)
MD5: 45C1170FF40D5C901A42A9D477D3C3CD
 
URL https://doi.org/10.1039/D5SM01184A
 
Language:English
Work type:Scientific work
Typology:1.01 - Original Scientific Article
Organization:FNM - Faculty of Natural Sciences and Mathematics
Abstract:Coalescence of droplets on liquid-infused surfaces has been extensively investigated for isotropic lubricants, where interfacial and hydrodynamic responses are well described by geometry-based and mass-spring models. However, the corresponding dynamics on anisotropic lubricating films, such as liquid crystals (LCs), remain largely unexplored. In this work, we report the use of high-speed imaging to study the attraction and coalescence of millimetre-sized water droplets on two classes of substrates, covered with a thin LC overlayer: LC-infused textured surfaces (LCITS) and LC-infused porous surfaces (LCIPS). On both substrates, the droplets coalesce through three stages over approximately one minute: long-range capillary-mediated attraction, drainage of the lubricant within the wetting ridge, and final merging accompanied by in-plane oscillations of the formed droplet. On LCITS, the initial approach velocities and post-merging dynamics are broadly consistent with the geometry-based mass–spring model developed for oil-impregnated surfaces of a similar type. However, on LCIPS, where a thicker lubricating film produces a larger wetting ridge, we observe substantially reduced attraction and merging velocities, no oscillations were resolved within our temporal resolution at the f irst velocity peak, and drainage times strongly influenced by evaporation. In the final stage, the peak velocity mainly depends on the LC mesophase and is nearly independent of droplet size, while the oscillation period scales approximately with the square root of the droplet radius. These results clarify how the porous LC scaffold and enlarged wetting ridge alter droplet-droplet interactions and coalescence dynamics relative to textured silicone substrates.
Keywords:droplet coalescence, capillary forces, anisotropic lubricating films, liquid crystals
Publication status:Published
Publication version:Version of Record
Article acceptance date:25.02.2026
Publication date:25.02.2026
Publisher:Royal Society of Chemistry
Year of publishing:2026
Number of pages:12 str.
PID:20.500.12556/DKUM-97352 New window
UDC:532.783
ISSN on article:1744-6848
COBISS.SI-ID:270070787 New window
DOI:10.1039/D5SM01184A New window
Publication date in DKUM:02.03.2026
Views:129
Downloads:3
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Soft matter
Shortened title:Soft matter
Publisher:Royal Society of Chemistry
ISSN:1744-6848
COBISS.SI-ID:23741223 New window

Document is financed by a project

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:P1-0055-2022
Name:Biofizika polimerov, membran, gelov, koloidov in celic

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:J2-50092-2023
Name:Kvantitativna volumetrična mikroskopija za karakterizacijo kapljičnih emulzij in tekočih kristalov v mikrofluidičnih okoljih brez označevanja

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:BI-US/24-26-087-2024
Name:Dinamika vodnih kapljic na mikrostrukturiranih tekočekristalnih površinah

Licences

License:CC BY-NC 4.0, Creative Commons Attribution-NonCommercial 4.0 International
Link:http://creativecommons.org/licenses/by-nc/4.0/
Description:A creative commons license that bans commercial use, but the users don’t have to license their derivative works on the same terms.
Licensing start date:25.02.2026

Secondary language

Language:Slovenian
Keywords:koalescenca kapljic, kapilarne sile, anizotropni mazalni filmi, tekoči kristali


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