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Title:Microplastic pollution in vulnerable karst environments : case study from the Slovenian classical karst region
Authors:ID Valentić, Lara (Author)
ID Kozel, Peter (Author)
ID Pipan, Tanja (Author)
Files:.pdf Valentic-2022-MICROPLASTIC_POLLUTION_IN_VULNER.pdf (2,36 MB)
MD5: 87E1EBDA9F3CA0A8353F1BB3CD024580
 
URL https://doi.org/10.3986/ac.v51i1.10597
 
Language:English
Work type:Scientific work
Typology:1.01 - Original Scientific Article
Organization:FNM - Faculty of Natural Sciences and Mathematics
Abstract:Since the start of mass production of plastic materials more than a century ago, the problem of accumulating plastic waste in the environment has reached epic proportions. Recently, the problem of smaller plastic particles (microplastic, MP) in the environment has become a widely studied topic, but the amount and types of MP in karst environments are still poorly known. Thus, the objective of this study was to collect and analyse samples from various karst habitats and to try and determine the scope of pollution in karst springs that are in part used as sources for drinking water. Of the potential pollution sources, we sampled rainwater, two discharges from wastewater treatment plants, and a leachate from a landfill. We conducted polymer analyses of potential MP particles using FTIR-ATR. The results showed that eight samples from the Postojna region (Postojna–Planina Cave System, rainfall sample and surface streams) contain up to 444 MP particles per m3. However, 32 samples taken from the Škocjan–Kačna–Jama 1 v Kanjaducah Cave System contain up to 60,000 MP particles per m3, with the bulk of particles found in the sediment samples from Škocjan Caves – Kačna Cave System. Samples from Postojna region contained mostly PET, PU and PA polymers, with a minor inclusion of polymers of plastic sponge used for cleaning. Samples from Škocjan region contained mostly PP, PET and PE polymers, with some of PA and PU polymers. Sediment samples contained much less MP particles compared to water samples, which indicates fast transport through karst aquifer.
Keywords:caves, fibres, microplastic contamination, karst (geology), groundwater, pollution, plastics, aquifers, Postojna (Slovenia), Škocjan (Slovenia)
Publication status:Published
Publication version:Version of Record
Submitted for review:02.02.2022
Publication date:08.12.2022
Publisher:Slovenska akademija znanosti in umetnosti
Year of publishing:2022
Number of pages:Str. 79-92
Numbering:Letn. 51, Št. 1
PID:20.500.12556/DKUM-89480 New window
UDC:551.435.8:504.5:691.175(497.47)
ISSN on article:0583-6050
COBISS.SI-ID:133496067 New window
DOI:10.3986/ac.v51i1.10597 New window
Publication date in DKUM:12.07.2024
Views:242
Downloads:37
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Acta carsologica
Shortened title:Acta carsol.
Publisher:Slovenska akademija znanosti in umetnosti
ISSN:0583-6050
COBISS.SI-ID:6427138 New window

Document is financed by a project

Funder:ARRS - Slovenian Research Agency
Project number:P6-0119
Name:Raziskovanje krasa

Funder:ARRS - Slovenian Research Agency
Project number:NK-0002
Name:Ekohidrološka študija prostorsko-časovne dinamike v kraških kritičnih conah v različnih podnebnih razmerah

Funder:Other - Other funder or multiple funders
Project number:C3330-19-952062
Name:Development of Research infrastructure for international competitiveness of the Slovenian RRI space
Acronym:RI-SI-LifeWatch

Funder:Other - Other funder or multiple funders
Name:eLTER Preparatory Phase Project
Acronym:eLTER PPP

Funder:Other - Other funder or multiple funders
Name:Integrated European Long-Term Ecosystem, critical zone and socio-ecological Research infrastructure Advanced Community project
Acronym:eLTER PLUS

Funder:Other - Other funder or multiple funders
Name:European Long-Term Ecosystem, critical zone and socio-ecological systems Research Infrastructure
Acronym:eLTER RI

Funder:Other - Other funder or multiple funders
Name:e-Science and Technology European Infrastructure for Biodiversity and Ecosystem Research
Acronym:LifeWatch ERIC

Licences

License:CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Link:http://creativecommons.org/licenses/by-nc-nd/4.0/
Description:The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.
Licensing start date:08.12.2022

Secondary language

Language:Slovenian
Title:Onesnaževanje z mikroplastiko v ranljivem kraškem svetu : primer slovenskega klasičnega krasa
Abstract:Z začetkom proizvodnje plastičnih polimerov pred več kot stoletjem se je pojavil pereč problem kopičenja plastičnih odpadkov v okolju. V zadnjih letih se problematika majhnih delcev plastike (mikroplastike, MP) pospešeno proučuje, kljub vsemu je malo znanega o količinah in vrstah MP v kraškem okolju. Namen te raziskave je bil odvzeti in analizirati vzorce iz kraških habitatov ter poskusiti določiti onesnaženje z mikroplastiko v kraških izvirih, ki se uporabljajo kot viri pitne vode. Od potencialnih virov onesnaženja smo vzorčili deževnico, izpust očiščene vode iz dveh komunalnih čistilnih naprav in izcedne vode iz smetišča. Analize polimerov potencialnih MP delcev smo opravili z metodo FTIR-ATR. Rezultati so pokazali, da osem vzorcev s postojnskega območja (Postojnskoplaninski jamski sistem, vzorec deževnice in vzorci površinskih voda) vsebuje do 444 MP delcev na m3. Po drugi strani 32 odvzetih vzorcev iz jamskega sistema Škocjanske jame: Kačna jama ‒ Jama 1 v Kanjaducah vsebuje do 60.000 MP delcev na m3, z najvišjo koncentracijo vlaken MP v jamskem sistemu Škocjanske jame: Kačna jama. Rezultati polimerne analize so pokazali, da vzorci s postojnskega območja vsebujejo največ PET, PU in PA polimere, z majhnim deležem polimerov, ki imajo podoben spekter kot plastična gobica za čiščenje. Vzorci s škocjanskega območja so vsebovali večinoma PP, PET in PE polimere, z manjšim deležem PA in PU polimerov. Vzorci sedimenta so vsebovali precej manj MP delcev kot vodni vzorci, kar kaže na hiter prenos onesnaženja skozi kraški vodonosnik.
Keywords:jame, vlakna, onesnaženje z mikroplastiko, kras (geologija), podzemne vode, onesnaževanje, plastika, vodonosniki, Postojna (Slovenija), Škocjan (Slovenija)


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