| Title: | Myrcene-based porous polymers via emulsion templating and thiol-ene polymerization |
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| Authors: | ID Koler, Amadeja (Author)
ID Krajnc, Peter (Author) |
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| Files: |  s00706-025-03360-2.pdf (777,56 KB)
MD5: 331C2668059956DA3C32F1DBD06D6C5E
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| Language: | English |
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| Work type: | Article |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: | FKKT - Faculty of Chemistry and Chemical Engineering
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| Abstract: | Porous polymer networks were synthesized via thiol-ene photo-polymerization using a naturally occurring terpene, myrcene and the multifunctional thiol, trimethylolpropane tris(3-mercaptopropionate). A highly porous structure (up to 80% porosity) was achieved by polymerizing the monomeric phase of high internal phase emulsions (HIPEs), composed of myrcene and trimethylolpropane tris(3-mercaptopropionate) in the presence of ethylene glycol dimethacrylate, which facilitated the formation of polyHIPE materials. Myrcene was incorporated in concentrations ranging from 9 to 40 mol%, and its content was found to significantly influence the resulting polymer morphology. Depending on the formulation, both bicontinuous-like and open-cell polyHIPE morphologies were obtained. In addition to myrcene content, the thiol-to-alkene functional group ratio (1:1 ratio of thiol to alkene groups, as well as formulations with an excess of alkene functionalities relative to thiols). |
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| Keywords: | photochemistry, terpenes, thiol-ene reaction, polyHIPEs, myrcene |
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| Publication status: | Published |
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| Publication version: | Version of Record |
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| Submitted for review: | 26.04.2025 |
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| Article acceptance date: | 19.07.2025 |
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| Publication date: | 04.08.2025 |
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| Publisher: | Springer |
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| Year of publishing: | 2025 |
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| Number of pages: | 7 str. |
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| PID: | 20.500.12556/DKUM-94207  |
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| UDC: | 66 |
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| ISSN on article: | 1434-4475 |
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| COBISS.SI-ID: | 245079299 |
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| DOI: | 10.1007/s00706-025-03360-2 |
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| Copyright: | © The Author(s) 2025
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| Publication date in DKUM: | 08.08.2025 |
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| Views: | 185 |
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| Downloads: | 16 |
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| Metadata: |    |
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| Categories: | Misc.
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