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Title:Adsorption Equilibrium Modelling for Different Temperature Conditions and Its Influence on Adsorption Mass Transfer
Authors:ID Štimec, Teodor (Author)
ID Hriberšek, Matjaž (Author)
ID Ravnik, Jure (Author)
ID Bašič, Sani Marko (Author)
ID Zadravec, Matej (Author)
Files:.pdf RAZ_Stimec_Teodor_2016.pdf (1,33 MB)
MD5: D4C1B166FCD3CD7688DC872FBEB54820
 
URL https://journals.um.si/index.php/anali-pazu/en/article/view/1973
 
Language:English
Work type:Scientific work
Typology:1.01 - Original Scientific Article
Organization:UZUM - University of Maribor Press
Abstract:The paper deals with numerical modelling of adsorption kinetics in a narrow channel of a honeycomb type adsorber. The mass transfer model consists of solving the diffusion-convection transport equation for adsorbate species in the fluid phase. The adsorbate flux to the wall is computed implicitly by using the Boundary Element Method for the solution of the transport equation. Scalable boundary condition for the adsorbate concentration on the adsorbent walls is used, defined on basis of the ratio of the accumulated adsorbate mass and the equilibrium adsorbate mass for a given system temperature. As the state of equilibrium is dependent also on the system temperature, a sensitivity study of the adsorption process under different system temperatures is performed. Among the studied adsorption equilibria models, including the Freundlich model, Simplified local density (SLD) model and the Dubinin-Radushkevich model, the latter is proved as the best compromise between accuracy and computational cost and applied in mass transfer kinetics computations. The results of computations show, that the increase in system temperature results in a decrease of breakthrough times, as the equilibrium amounts of adsorbate at the adsorbent walls decrease with increasing temperature, therefore making the derived numerical model suitable for further use in detailed mass transfer kinetics computations.
Keywords:subdomain boundary element method, laminar viscous fluid flow, mass transfer, adsorption, honeycomb adsorber
Publication status:Published
Publication version:Version of Record
Publication date:01.01.2016
Place of publishing:Maribor
Publisher:Univerza v Mariboru, Univerzitetna založba
Year of publishing:2016
Number of pages:7
Numbering:Letn.5, št.1/2
PID:20.500.12556/DKUM-97360 New window
UDC:532.13
ISSN on article:2820-364X
COBISS.SI-ID:19638550 New window
DOI:10.18690/analipazu.5.1-2.26-32.2015 New window
Publication date in DKUM:02.03.2026
Views:166
Downloads:2
Metadata:XML DC-XML DC-RDF
Categories:Misc.
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Record is a part of a journal

Title:Anali PAZU
Publisher:Združenje Pomurska akademsko znanstvena unija, Združenje Pomurska akademsko znanstvena unija, Univerzitetna založba Univerze v Mariboru
ISSN:2232-416X
COBISS.SI-ID:257553152 New window

Licences

License:CC BY-NC-ND 4.0, Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
Link:http://creativecommons.org/licenses/by-nc-nd/4.0/
Description:The most restrictive Creative Commons license. This only allows people to download and share the work for no commercial gain and for no other purposes.

Secondary language

Language:Slovenian
Title:Modeliranje adsorpcijskega ravnotežja v različnih temperaturnih pogojih in njegov vpliv na prenos snovi pri adsorpciji
Abstract:V prispevku je predstavljen numerični model za simulacijo adsorpcijskega procesa v kanalu, ki ima na svojih stenah nameščeno plast adsorbenta. V kanalu teče tok nosilnega plina z zelo nizko koncentracijo adsorbata, ki adsorbira v plast adsorbenta. Prenos snovi je simuliran z reševanjem difuzivno-konvektivne prenosne enačbe ohranitve mase adsorbata, diskretizirane z metodo robnih elementov. Adsorpcijski proces je modeliran s prilaganjem vrednosti robne koncentracije, ki je odvisna od razmerja med akumulirano ter ravnotežno množino adsorbata v plasti adsorbenta. Ker se ravnotežno stanje spreminja s temperaturo sistema je v prispevku prikazan vpliv le te na ravnotežno stanje. Ravnotežna množina adsorbata v plasti adsorbenta je določena s Freundlich. SLD in Dubinin-Radushkevich ravnotežnim modelom, kjer se slednji izkaže za najboljšo izbiro glede na natančnost rezultatov in računski čas. Rezultati izvedenih preračunov kažejo, da se s povečevanjem temperature v sistemu zniža čas pri katerem pride do preboja adsorbata, ker se ravnotežna količina adsorbata na stenah adsorbenta zmanjšuje s povečevanjem temperature sistema. Izdelana numerična rutina omogoča natančno simuliranje adsorpcijskih procesov v kanalu ter napovedovanje prebojne koncentracijske krivulje adsorbata.
Keywords:podobmočna metoda robnih elementov, laminarni viskozni tok tekočine, prenos snovi, adsorpcija, adsorber s satovjem


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  1. Anali PAZU

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